Catalytic stereodivergent functionalization of H2@C60.
نویسندگان
چکیده
A complete stereocontrol of 1,3-dipolar cycloaddition of N-metalated azomethine ylides onto endohedral fullerene H2@C60 is reported for the first time. The stereodivergent synthesis of either the cis or the trans endohedral cycloadduct is achieved with excellent diastereo- and enantioselectivities.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 6 شماره
صفحات -
تاریخ انتشار 2014